Jude Law as Sky Captain

Gwyneth Paltrow as Polly Perkins

Angelina Jolie as Franky

Giovanni Ribisi as Dex

Michael Gambon as Paley

Bai Ling as Mysterious Woman

Omid Djalili as Kaji

Laurence Olivier as Dr. Totenkopf (archive footage)

Trevor Baxter as Dr Walter Jennings

Julian Curry as Dr. Vargas

Peter Law as Dr. Kessler

Jon Rumney as German Scientist

Khan Bonfils as Creepy

Samta Gyatso as Scary

Louis Hilyer as Executive Officer

Mark Wells as Communication Engineer

James Cash as Uniformed Officer

Tenzin Bhagen as Kalacakra Priest

Thupten Tsondru as Dying Old Man

Matthew Grant as Crewman #1

Steve Morphew as Crewman #2

Nancy Crane as Receptionist

Stuart Milligan as Police Sergeant

Paul Canter as Police Officer

Demetri Goritsas as Radio Operator

William Hope as American Broadcaster

Jonathan Keeble as British Broadcaster

Stéphane Cornicard as French Broadcaster

Stephen Ballantyne as German Broadcaster

Victor Sobchak as Russian Broadcaster

Mido Hamada as Soldier

Gerard Monaco as Technician

Chris Robson as Hindenburg Porter

Matthew Coulter as Hindenburg Boy

Merritt Yohnka as Construction Worker

Charlotte Kyle as Hindenberg Passenger (uncredited)

James Bannon as Voice Actor (uncredited)

Karl Champley as Pilot (uncredited)

David Decio as Pilot (uncredited)

Matthew Feitshans as Officer (uncredited)

Sky Soleil as Officer (uncredited)

Chuen Tsou as Buddhist Monk (uncredited)