Betty Hutton as Annie Oakley

Howard Keel as Frank Butler

Louis Calhern as Col. Buffalo Bill Cody

J. Carrol Naish as Chief Sitting Bull

Edward Arnold as Pawnee Bill

Keenan Wynn as Charlie Davenport

Benay Venuta as Dolly Tate

Clinton Sundberg as Foster Wilson

Evelyn Beresford as Queen Victoria (uncredited)

Mae Clarke as Mrs. Adams (uncredited)

John Hamilton as Ship Captain (uncredited)

William Tannen as Barker (uncredited)

Dorinda Clifton as Cowgirl (uncredited)

Bette Arlen as Carriage Passenger (uncredited)