Chris Evans as Steve Rogers / Captain America

Robert Downey Jr. as Tony Stark / Iron Man

Scarlett Johansson as Natasha Romanoff / Black Widow

Sebastian Stan as Bucky Barnes / Winter Soldier

Anthony Mackie as Sam Wilson / Falcon

Don Cheadle as Lieutenant James Rhodes / War Machine

Jeremy Renner as Clint Barton / Hawkeye

Chadwick Boseman as T'Challa / Black Panther

Paul Bettany as Vision

Elizabeth Olsen as Wanda Maximoff / Scarlet Witch

Paul Rudd as Scott Lang / Ant-Man

Emily VanCamp as Sharon Carter

Tom Holland as Peter Parker / Spider-Man

Daniel Brühl as Zemo

Frank Grillo as Brock Rumlow / Crossbones

William Hurt as Secretary of State Thaddeus Ross

Martin Freeman as Everett K. Ross

Marisa Tomei as May Parker

John Kani as King T'Chaka

John Slattery as Howard Stark

Hope Davis as Maria Stark

Alfre Woodard as Miriam

Michael A. Cook as MRI Tech

Laughton Parchment as Vicar

Jackson Spidell as Josef / Super Soldier #1

Yi Long as Super Soldier #2

Heidi Moneymaker as Super Soldier #3

Aaron Toney as Super Soldier #4

Cale Schultz as Super Soldier #5

Ann Russo as Zemo's Wife (voice)

Gene Farber as Karpov

Florence Kasumba as Security Chief

Cornell John as Attaché

Sven Hönig as Man at Kiosk

Joshua Peck as GSG9 Task Force Gunner

Brent McGee as GSG9 Task Force Pilot

Be Satrazemis as German Innkeeper

Blair Jasin as Raft Guard

Oliver Bigalke as Barge Man #1

Rafael Banasik as Barge Man #2

David de Vries as Custodian

John Curran as Funeral Director

Katie Amess as Woman in Lobby #1

Austin Sanders as Woman in Lobby #2

Brett Gentile as Delivery Truck Driver

Matthew Anderson as Choir

Andrew Botchwey as Choir

Chase Bradfield as Choir

Ernest Charles as Choir

Hendricks Coates as Choir

Ethan Condon as Choir

Shen Dynes as Choir

Nathaniel Ellis as Choir

Jariah Ferguson as Choir

Evan Ffrench as Choir

Justin Freeman as Choir

Ralphael Grand'Pierre as Choir

Julian Grimes as Choir

Aaron Hayes as Choir

Austin Hooper as Choir

Amiri Jones as Choir

Myles Joseph as Choir

Stephen Lewis as Choir

Jacob Ludwick as Choir

D'Mahrei McRae as Choir

Ashwin Mudaliar as Choir

Eli Ollinger as Choir

Parker Pape as Choir

Daniel Parada as Choir

Jonah Ruffin as Choir

Darryl Sampson as Choir

Cameron Sardone as Choir

Stanley Sellers as Choir

Miles Selles as Choir

Jacob Sung as Choir

Caden Wilkinson as Choir

Jin Shijia as Chinese Newscaster

Jessica Walther-Gabory as German Newscaster #1

Beniamino Brogi as German Newscaster #2

Silvina Buchbauer as News Reporter

Henry Amadi as Busboy (Lagos)

Ugochukwu Ani as Waiter (Lagos)

Michael Anthony Rogers as Secretary Ross's Aide

Damion Poitier as Hero Merc #1

Umar Khan as Hero Merc #2

David E. Brown as Hero Merc #3

Guy Fernandez as Hero Merc #4

Jim Rash as M.I.T. Liaison

Sophia Russo as Teenage Girl

Joe Russo as Dr. Broussard

Stan Lee as FedEx Driver

Amelia Morck as UN Staffer Gibson

Kerry Condon as Friday (voice)

Julianna Guill as Stark's Assistant

Surely Alvelo as Nurse

Brian Schaeffer as Cultural Attaché

Kevin LaRosa Jr. as Helicopter Pilot

Al Cerullo as Helicopter Pilot

Frédéric North as Helicopter Pilot

Ray Sahetapy as Auctioneer (uncredited)

Chris Jai Alex as IFID (uncredited)

Scott Hunter as Crossbones’ Mercenary (uncredited)

Kimberly Hester Huffstetler as MIT Graduate Student (uncredited)

Kevin Christenson as Funeral Mourner (uncredited)