Barbara Stanwyck as Annie Oakley

Preston Foster as Toby Walker

Melvyn Douglas as Jeff Hogarth

Moroni Olsen as Col. William F. 'Buffalo Bill' Cody

Pert Kelton as Vera Delmar

Andy Clyde as James MacIvor

Chief Thunderbird as Sitting Bull (as Chief Thunder Bird)

Margaret Armstrong as Mrs. Oakley

Delmar Watson as Wesley Oakley

Adeline Craig as Susan Oakley